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IAEI News>Issue Listing>November/December 2001 >A Fuel Cell Primer
A fuel cell is an electrochemical device that combines hydrogen and oxygen to produce electricity, with water and heat as the by-product. A fuel cell is similar in structure to a battery but it does not run down, nor does it require recharging — as long as hydrogen is supplied, it will continue to operate. The conversion of the fuel (hydrogen) to energy takes place without combustion; therefore the process is highly efficient, clean and quiet. Fuel cells are really a family of technologies. Five major types, characterized by their electrolytes, are being developed: Proton Exchange Membrane (PEMFC), Alkaline (AFC), Phosphoric Acid (PAFC), Molten Carbonate (MCFC) and Solid Oxide (SOFC). Direct Methanol Fuel Cells (DMFCs) are a type of PEMFC that directly uses methanol as the fuel. A fuel cell consists of two electrodes separated by an electrolyte. In most cases, hydrogen fuel is fed into the anode of the fuel cell. Oxygen (or air) enters the fuel cell at the cathode. Encouraged by a catalyst, the hydrogen splits into protons and electrons. The protons pass through the electrolyte. The electrons must take the long way around, creating a separate current that can be utilized before they return to the cathode, to be reunited with the hydrogen and oxygen to form a molecule of water. Individual cells are "stacked" together to generate useful quantities of power. Higher temperature systems (MCFC, SOFC, PAFC) tend to be best suited to larger applications, while low temperature systems (PEMFC, DMFC, AFC) can be configured to provide as little as a few watts of power, or less. All fuel cells are modular. Units ranging in size from a few kilowatts to approximately 250 kW can be used as building blocks for larger systems. Fuel
Flexibility Applications
for Fuel Cells Stationary/Distributed
Power Applications The option of distributed power supply, also called "microgeneration," is gaining converts as a more sensible approach than traditional grid systems. Fuel cells are considered an important emerging distributed generation technology. Benefits of
Fuel Cells for Stationary/Distributed Power Applications Fuel cell systems can provide on-site power, easing the strain on the existing centralized power grid, and reducing inefficiencies due to transmission losses. The modularity of fuel cells allows for incremental buildup of capacity where there is minimal funding available for the up-front capital costs of multi-megawatt sized or centralized power plants. And they can be configured to provide backup power to a grid connected customer, should the grid fail. Because fuel cells generate heat as a by-product, there are co-generation possibilities for fuel cells installed on-site. The potential total efficiency of these Combined Heat and Power (CHP) systems can exceed 80 percent. Fuel cells are environmentally preferable to traditional power generation technologies. The first commercially available fuel cell power plants, produced by International Fuel Cells, create less than one ounce of pollution per 1,000 kilowatt hours of electricity produced — compared to the 25 pounds of pollutants for conventional combustion generating systems. Fuel cell power plants are so clean, some areas of the United States have exempted them from air permit requirements. The high reliability of fuel cells makes them an attractive option for businesses that are willing to pay a premium for power because the costs of losing power are great. According to Contingency Planning Research (1996), the average cost of down time for Credit Card Operations is $6.48 million per hour. An Alaska mail processing center installed five fuel cells, totaling 1 MW, as the primary source of power. If there is a grid outage, the installation will automatically operate as an independent system, continuing to power the facility. Status
of Development On the way are units for homes (see photo 2). IdaTech is delivering 110 residential fuel cell units to Bonneville Power for demonstration in the Northwestern United States. Long Island Power Authority will be demonstrating 75 fuel cell units produced by Plug Power. And H Power received an order for 12,300 fuel cells from Energy Co-Opportunity, a consortium of rural electric cooperatives, which expects to begin marketing and installing the units by the end of 2001. Transportation
Applications Even though there has been progress in reducing pollution emitted by newer vehicles, those gains are offset by the increased amount of driving and the rising number of vehicles on the roads. There are days when vehicles are banned from the downtown areas of Rome, Paris, Athens and Mexico City due to high pollution. In many major cities, scooters with two-stroke engines are significant contributors to smog. Benefits
of Fuel Cells for Transportation Applications Using fuel cells in locomotives, buses or heavy-duty trucks means air conditioning and heating units can be powered without having to idle the diesel engines. Tests performed on Georgetown University’s second generation fuel cell bus, using methanol as the fuel, showed zero emissions of particulate matter and hydrocarbons, and near-zero emissions of carbon monoxide and nitrous oxides — levels far below the 1998 emission standard for buses. Status
of Development In the area of heavy-duty vehicle applications, Freightliner is demonstrating a Class 8 truck with a fuel cell auxiliary power unit. The fuel cell will allow the truck driver to run air conditioning, a television, or other appliances without having to idle the engine or drain the battery. Fuel cell powered boom lifts, forklifts, golf carts and utility vehicles are being demonstrated around the world. BMW has said it will develop hydrogen fueled fuel cell forklift trucks, deploying about 2,000 in the company’s own facilities before marketing them to other users. Fuel cells are also being demonstrated on small passenger boats, and Siemens has built and tested a fuel cell that is to be used in all of the German Navy’s future 212-class submarines, due to be commissioned beginning in 2003. Portable
Power Applications Benefits
of Fuel Cells for Portable Power Applications Manhattan Scientifics expects a fuel cell powered cell phone to have up to 200-hours of talk time. Recharging fuel cell powered electronic devices could be as simple as inserting a small cartridge of methanol (like a new ink cartridge in a pen), instead of waiting several hours for a battery to recharge, or carrying replacement batteries. The U.S. Army is looking into fuel cells to replace batteries for powering field equipment. Status
of Development ABI’s report projects that "wireless handsets are the initial market for the first wave of portable fuel cells," starting with 50,000 units shipped in 2002, and ramping up to 200 million units by 2007. Conclusion On the vehicle side, issues of fueling infrastructure are critical and must be addressed. While reformers are being developed to allow fuel cells to be used with the existing fueling infrastructure, research and development must also focus on facilitating the distribution of cleaner alternative transportation fuels. Infrastructure issues for fuel cell buses are not such a concern, since the vehicles are refueled at a central location. The efficiency, reliability and environmental benefits of fuel cells make it a key technology for all types of power needs. The unique qualities of fuel cell technology make it an attractive option for powering homes and buildings, vehicles, and a multitude of electronic devices — allowing world economies to thrive without putting further strain on the environment or its natural resources. Bernadette Geyer is Director of Outreach Programs for the U.S. Fuel Cell Council, and edits a monthly and a quarterly newsletter for the organization. Her articles on fuel cell technology have appeared in such publications as Sustainable Development International, Hydrogen & Fuel Cell Letter, and Standard & Poors' Utilities & Perspectives.
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